Ok, five slots are already filled. Cleric, warrior, ranger, wizard, and a enchater. Now the group already has a tank, healer, 2 dps, and a mezzer. Who would you prefer got the last slot? Another DPS or a tank (warrior, shadowknight, or paladin.)
I say paladin makes the best support class and I have several reasons.
Back-up tank. Something goes down and you got like 3 mobs attacking you. The paladin can stun a mob and take agro from another until the enchanter can mez.
Back-up healer. Something happens to the cleric, but the warrior will die before the cleric can pull off a CH. Paladins get special spells that have a fast casting time, but a lower hp heal, great to keep him alive until the cleric can heal.
**** goes down. The cleric or the enchanter are dieing fast and they are basically the only two classes that can save the group in the long run. Hand of Piety or LoH (possibly act of valor =D) and save one so they can crowd controll or heal the group, thus saving it.
Pulling. Paladins are really good at pulling. They may not be the best, but damn they are good.
Now paladins cannot necessarily be the best tank, but they are great to have in the group and can preform the jobs of the two classes he is made of when needed.